A quinoxaline-fused tetrathiafulvalene-based sensitizer for efficient dye-sensitized solar cells

被引:70
作者
Amacher, Anneliese [1 ]
Yi, Chenyi [2 ]
Yang, Jiabao [2 ,3 ,4 ]
Bircher, Martin Peter [1 ]
Fu, Yongchun [1 ]
Cascella, Michele [5 ,6 ]
Graetzel, Michael [2 ]
Decurtins, Silvio [1 ]
Liu, Shi-Xia [1 ]
机构
[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland
[2] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1050 Lausanne, Switzerland
[3] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[4] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
[5] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
[6] Univ Oslo, CTCC, N-0315 Oslo, Norway
基金
瑞士国家科学基金会;
关键词
INTRAMOLECULAR CHARGE-TRANSFER; DONOR-ACCEPTOR DYAD; BUILDING-BLOCKS; ORGANIC-DYES; CHEMISTRY; TTF; MOLECULE;
D O I
10.1039/c4cc02696a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new quinoxaline-fused tetrathiafulvalene-based sensitizer has been prepared and characterized. The resulting power conversion efficiency of 6.47% represents the best performance to date for tetrathiafulvalene-sensitized solar cells.
引用
收藏
页码:6540 / 6542
页数:3
相关论文
共 31 条
[1]  
Batail P., 2004, Chem Rev, V104
[2]   Tetrathiafulvalene (TTF) derivatives: key building-blocks for switchable processes [J].
Canevet, David ;
Salle, Marc ;
Zhang, Guanxin ;
Zhang, Deqing ;
Zhu, Daoben .
CHEMICAL COMMUNICATIONS, 2009, (17) :2245-2269
[3]   Sensitizer molecular structure-device efficiency relationship in dye sensitized solar cells [J].
Clifford, John N. ;
Martinez-Ferrero, Eugenia ;
Viterisi, Aurelien ;
Palomares, Emilio .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1635-1646
[4]   Photophysical, electrochemical and photovoltaic properties of dye sensitized solar cells using a series of pyridyl functionalized porphyrin dyes [J].
Daphnomili, Dimitra ;
Landrou, Giorgos ;
Singh, Surya Prakash ;
Thomas, Anup ;
Yesudas, Kada ;
Bhanuprakash, K. ;
Sharma, G. D. ;
Coutsolelos, A. G. .
RSC ADVANCES, 2012, 2 (33) :12899-12908
[5]   Inter- and intramolecular interactions in some supramolecular photochemical systems [J].
Delahaye, S ;
Loosli, C ;
Liu, SX ;
Decurtins, S ;
Labat, G ;
Neels, A ;
Loosli, A ;
Ward, TR ;
Hauser, A .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (02) :286-295
[6]   A quinoxaline-fused tetrathiafulvalene derivative and its semiconducting charge-transfer salt: synthesis, crystal structures and physical properties [J].
Geng, Yan ;
Fiolka, Christoph ;
Kraemer, Karl ;
Hauser, Juerg ;
Laukhin, Vladimir ;
Decurtins, Silvio ;
Liu, Shi-Xia .
NEW JOURNAL OF CHEMISTRY, 2014, 38 (05) :2052-2057
[7]   Pronounced Electrochemical Amphotericity of a Fused Donor-Acceptor Compound: A Planar Merge of TTF with a TCNQ-Type Bithienoquinoxaline [J].
Guegano, Xavier ;
Kanibolotsky, Alexander L. ;
Blum, Carmen ;
Mertens, Stijn F. L. ;
Liu, Shi-Xia ;
Neels, Antonia ;
Hagemann, Hans ;
Skabara, Peter J. ;
Leutwyler, Samuel ;
Wandlowski, Thomas ;
Hauser, Andreas ;
Decurtins, Silvio .
CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (01) :63-66
[8]   Dye-Sensitized Solar Cells [J].
Hagfeldt, Anders ;
Boschloo, Gerrit ;
Sun, Licheng ;
Kloo, Lars ;
Pettersson, Henrik .
CHEMICAL REVIEWS, 2010, 110 (11) :6595-6663
[9]   A Compactly Fused π-Conjugated Tetrathiafulvalene-Perylenediimide Donor-Acceptor Dyad [J].
Jaggi, Michael ;
Blum, Carmen ;
Dupont, Nathalie ;
Grilj, Jakob ;
Liu, Shi-Xia ;
Hauser, Juerg ;
Hauser, Andreas ;
Decurtins, Silvio .
ORGANIC LETTERS, 2009, 11 (14) :3096-3099
[10]   An experimental and computational study on intramolecular charge transfer: A tetrathiafulvalene-fused dipyridophenazine molecule [J].
Jia, Chunyang ;
Liu, Shi-Xia ;
Tanner, Christian ;
Leiggener, Claudia ;
Neels, Antonia ;
Sanguinet, Lionel ;
Levillain, Eric ;
Leutwyler, Samuel ;
Hauser, Andreas ;
Decurtins, Silvio .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (13) :3804-3812