Hydrogen Evolution at Liquid-Liquid Interfaces

被引：78

作者：

Hatay, Imren ^{[1
,2
]}

Siu, Bin ^{[1
]}

Li, Fei ^{[1
]}

Partovi-Nia, Raheleh ^{[1
]}

Vrubel, Heron ^{[3
]}

Hu, Xile ^{[3
]}

Ersoz, Mustafa ^{[2
]}

Girault, Hubert H. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Lab Electrochim Phys & Analyt, CH-1015 Lausanne, Switzerland

[2] Selcuk Univ, Dept Chem, TR-42031 Konya, Turkey

[3] Ecole Polytech Fed Lausanne, Lab Inorgan Synth & Catalysis, BCH 3305, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 28期

关键词：

hydrogren evolution; proton transfer; liquid-liquid interfaces; metallocenes; reduction; WATER; REDUCTION; COMPLEXES;

D O I：

10.1002/anie.200901757

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Blowing bubbles: Hydrogen evolution by proton reduction with [(C 5Me5)2Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C5Me5)2Fe] across the water-DCE interface with subsequent proton reduction in DCE. The interface essentially acts as a proton pump, allowing hydrogen evolution by directly using the aqueous proton. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5139 / 5142

页数：4

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