Determination of critical micelle concentration of surfactants by capillary electrophoresis

被引:64
作者
Lin, CE [1 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
关键词
reviews; critical micellar concentration; micellar electrokinetic chromatography; capillary electrophoresis; surfactants;
D O I
10.1016/j.chroma.2003.11.059
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Capillary electrophoresis (CE) has been proven to be a convenient and useful technique for the determination of the critical micelle concentration (CMC) of a surfactant in an electrophoretic system under operating conditions. In this review, methodological approaches to the determination of the CIVIC of surfactants by CE technique are described. The practical requirements for making such measurements and the CMC values of surfactants determined by CE methods are presented. In addition, difficulties and uncertainty, as well as misconceptions that may arise in the CMC determination are discussed. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:467 / 478
页数:12
相关论文
共 88 条
  • [11] A family of single-isomer chiral resolving agents for capillary electrophoresis.: 3.: Heptakis(2,3-dimethyl-6-sulfato)-β-cyclodextrin
    Cai, H
    Nguyen, TV
    Vigh, G
    [J]. ANALYTICAL CHEMISTRY, 1998, 70 (03) : 580 - 589
  • [12] CAMILLARI P, 1993, CAPILLARY ELECTROPHO
  • [13] Separation selectivity in micellar electrokinetic chromatography using different anionic surfactants as pseudo-stationary phases
    Chen, Z
    Yamada, K
    Niitsuma, M
    Uchiyama, K
    Hobo, T
    [J]. CHROMATOGRAPHIA, 2001, 54 (9-10) : 629 - 633
  • [14] Determination of critical micelle concentrations of anionic surfactants based on ligand exchange micellar electrokinetic chromatography
    Chen, ZL
    Lin, JM
    Uchiyama, K
    Hobo, T
    [J]. ANALYTICA CHIMICA ACTA, 2000, 403 (1-2) : 173 - 178
  • [15] Determination of critical micelle concentration values using capillary electrophoresis instrumentation
    Cifuentes, A
    Bernal, JL
    DiezMasa, JC
    [J]. ANALYTICAL CHEMISTRY, 1997, 69 (20) : 4271 - 4274
  • [16] Use of a fluorosurfactant in micellar electrokinetic capillary chromatography
    de Ridder, R
    Damin, F
    Reijenga, J
    Chiari, M
    [J]. JOURNAL OF CHROMATOGRAPHY A, 2001, 916 (1-2) : 73 - 78
  • [17] Determination of critical micelle concentration of some surfactants by three techniques
    Dominguez, A
    Fernandez, A
    Gonzalez, N
    Iglesias, E
    Montenegro, L
    [J]. JOURNAL OF CHEMICAL EDUCATION, 1997, 74 (10) : 1227 - 1231
  • [18] El Rassi Z, 1997, SELECTIVITY OPTIMIZA
  • [19] Esaka Y, 1996, J CHROMATOGR A, V736, P273
  • [20] Sodium dodecyl sulfate - Tween 20 mixed micellar electrokinetic chromatography for separation of hydrophobic cations: Application to adrenaline and its precursors
    Esaka, Y
    Tanaka, K
    Uno, B
    Goto, M
    Kano, K
    [J]. ANALYTICAL CHEMISTRY, 1997, 69 (07) : 1332 - 1338