Highly efficient catalyst precursor for ethanoic acid production: [RhCl(CO)(PEt3)(2)]; X-ray crystal and molecular structure of carbonyldiiodo(methyl)bis(triethylphosphine)rhodium(III)

被引：66

作者：

Rankin, J

Poole, AD

Benyei, AC

ColeHamilton, DJ

机构：

[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

[2] BP CHEM LTD,HULL RES & TECHNOL CTR,KINGSTON HULL HU12 8DS,N HUMBERSIDE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 19期

关键词：

D O I：

10.1039/a703895j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under mild conditions, [RhI(CO)(PEt3)(2)], is more active for the carbonylation of methanol to ethanoic acid than [Rh(CO)(2)I-2](-), which is widely used industrially; intermediates in the catalytic cycle have been identified and characterised.

引用

页码：1835 / 1836

页数：2

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