Charge-transfer emission in nonplanar three-coordinate organoboron compounds for fluorescent sensing of fluoride

被引:328
作者
Liu, Xiang Yang [1 ]
Bai, Dong Ren [1 ]
Wang, Suning [1 ]
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
关键词
boron; charge transfer; fluorescence; fluorides; sensors;
D O I
10.1002/anie.200601286
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A real turn-on: Two nonplanar three-coordinate boron compounds were synthesized as fluorescent sensors for fluoride that utilize charge-transfer emission. The fluorescence of one of the sensors turns on (see picture) and the other turns off in the presence of fluoride. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5475 / 5478
页数:4
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