Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts

被引：70

作者：

Klingshirn, MA

Broker, GA

Holbrey, JD

Shaughnessy, KH

Rogers, RD

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

[2] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 13期

关键词：

D O I：

10.1039/b203367d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium-catalyzed copolymerization of styrene and CO in an ionic liquid solvent, 1-hexylpyridinium bis(trifluoromethanesulfonyl) imide, gave improved yields and increased molecular weights compared to polymerizations run in methanol.

引用

页码：1394 / 1395

页数：2

共 23 条

[1] ABDULSADA AK, 1995, Patent No. 9521871
[2] How polar are room-temperature ionic liquids?
Aki, SNVK
Brennecke, JF
Samanta, A
[J]. CHEMICAL COMMUNICATIONS, 2001, (05) : 413 - 414
[3] Effect of the nature of metallocene complexes of group IV metals on their performance in catalytic ethylene and propylene polymerization
Alt, HG
Köppl, A
[J]. CHEMICAL REVIEWS, 2000, 100 (04) : 1205 - 1221
[4] [Anonymous], [No title captured], Patent No. 0032658
[5] STUDIES OF TITANIUM(IV) CHLORIDE IN A STRONGLY LEWIS ACIDIC MOLTEN-SALT - ELECTROCHEMISTRY AND TITANIUM NMR AND ELECTRONIC SPECTROSCOPY
CARLIN, RT
OSTERYOUNG, RA
WILKES, JS
ROVANG, J
[J]. INORGANIC CHEMISTRY, 1990, 29 (16) : 3003 - 3009
[6] COMPLEXATION OF CP2MCL2 IN A CHLOROALUMINATE MOLTEN-SALT - RELEVANCE TO HOMOGENEOUS ZIEGLER-NATTA CATALYSIS
CARLIN, RT
WILKES, JS
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1990, 63 (02): : 125 - 129
[7] Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide
Drent, E
Budzelaar, PHM
[J]. CHEMICAL REVIEWS, 1996, 96 (02) : 663 - 681
[8] Alternating copolymerisation of styrene and carbon monoxide in ionic liquids
Hardacre, C
Holbrey, JD
Katdare, SP
Seddon, KR
[J]. GREEN CHEMISTRY, 2002, 4 (02) : 143 - 146
[9] Late-metal catalysts for ethylene homo- and copolymerization
Ittel, SD
Johnson, LK
Brookhart, M
[J]. CHEMICAL REVIEWS, 2000, 100 (04) : 1169 - 1203
[10] Counterion effect on CO/styrene copolymerization catalyzed by cationic palladium(II) organometallic complexes: An interionic structural and dynamic investigation based on NMR spectroscopy
Macchioni, A
Bellachioma, G
Cardaci, G
Travaglia, M
Zuccaccia, C
Milani, B
Corso, G
Zangrando, E
Mestroni, G
Carfagna, C
Formica, M
[J]. ORGANOMETALLICS, 1999, 18 (16) : 3061 - 3069

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