Alternating copolymerisation of styrene and carbon monoxide in ionic liquids

被引：75

作者：

Hardacre, C ^{[1
]}

Holbrey, JD

Katdare, SP

Seddon, KR

机构：

[1] Queens Univ Belfast, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland

[2] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

来源：

GREEN CHEMISTRY | 2002年 / 4卷 / 02期

关键词：

D O I：

10.1039/b111157b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Room temperature ionic liquids have been used as solvents for the palladium-catalysed copolymerisation of styrene and carbon monoxide. The behaviour of various ionic liquids, the nature and concentration of palladium catalyst, and the reusability of the catalyst-ionic liquid system are discussed. The effects of cation, anion and alkyl chain length of the ionic liquids on the reaction are also addressed. The yield of the polyketone in the ionic liquid systems is enhanced over conventional solvents studied under similar conditions.

引用

页码：143 / 146

页数：4

共 35 条

[1] Clean and green ... but are they mean? [J].

Adam, D .

NATURE, 2000, 407 (6807) :938-940

[2] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[3] The Heck reaction in ionic liquids: A multiphasic catalyst system [J].

Carmichael, AJ ;

Earle, MJ ;

Holbrey, JD ;

McCormac, PB ;

Seddon, KR .

ORGANIC LETTERS, 1999, 1 (07) :997-1000

[4] Copper(I) mediated living radical polymerisation in an ionic liquid [J].

Carmichael, AJ ;

Haddleton, DM ;

Bon, SAF ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 2000, (14) :1237-1238

[5]

Chauvin Y, 1995, ANGEW CHEM INT EDIT, V34, P2698

[6] Molten salts (ionic liquids) to improve the activity, selectivity and stability of the palladium catalysed Trost-Tsuji C-C coupling in biphasic media [J].

de Bellefon, C ;

Pollet, E ;

Grenouillet, P .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 145 (1-2) :121-126

[7] Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide [J].

Drent, E ;

Budzelaar, PHM .

CHEMICAL REVIEWS, 1996, 96 (02) :663-681

[8] Pd(II)-dissolved in ionic liquids: A recyclable catalytic system for the selective biphasic hydrogenation of dienes to monoenes [J].

Dupont, J ;

Suarez, PAZ ;

Umpierre, AP ;

de Souza, RF .

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2000, 11 (03) :293-297

[9] Hydroformylation of 1-hexene with rhodium in non-aqueous ionic liquids: how to design the solvent and the ligand to the reaction [J].

Favre, F ;

Olivier-Bourbigou, H ;

Commereuc, D ;

Saussine, L .

CHEMICAL COMMUNICATIONS, 2001, (15) :1360-1361

[10] Ionic liquids prove increasingly versatile [J].

Freemantle, M .

CHEMICAL & ENGINEERING NEWS, 1999, 77 (01) :23-24

← 1 2 3 4 →