Facile oxygenation of organic sulfides with H2O2 catalyzed by Mn-Me3TACN compounds

被引：39

作者：

Barker, JE ^{[1
]}

Ren, T ^{[1
]}

机构：

[1] Univ Miami, Dept Chem, Coral Gables, FL 33146 USA

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 24期

关键词：

organic sulfide; catalytic oxygenation; Mn-Me(3)TACN; complexes; hydrogen peroxide;

D O I：

10.1016/j.tetlet.2004.04.125

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two binuclear Mn-Me(3)TACN (Me(3)TACN is 1,4,7-N,N',N"-trimethyl-1,4,7-triazacyclononane) compounds catalyze the oxygenation of organic sulfides utilizing H2O2 under ambient conditions. Both phenyl sulfide and ethyl phenyl sulfide were converted to the corresponding sulfones and chloroethyl phenyl sulfide proceeds to its elimination product of phenyl vinyl sulfone. (C) 2004 Elsevier Ltd. All rights reserved.

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收藏

页码：4681 / 4683

页数：3

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