A self-assembled pyrrolic cage receptor specifically recognizes β-glucopyranosides

被引:135
作者
Francesconi, Oscar
Ienco, Andrea
Moneti, Gloriano
Nativi, Cristina
Roelens, Stefano
机构
[1] CNR, Dipartimento Chim Organ, I-50019 Florence, Italy
[2] Univ Florence, Ctr Interdipartimentale Spettrometria Massa, I-50019 Florence, Italy
[3] CNR, Ist Chim Composti Organomet, I-50019 Florence, Italy
关键词
cage compounds; carbohydrates; molecular recognition; self-assembly; synthetic receptors;
D O I
10.1002/anie.200602412
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Fishing for β-glucose: Three dialdehydic and two triamino components quantitatively self-assemble into a pyrrolic cage receptor that effectively discriminates D-glucopyranosides among various monosaccharides and recognizes the β anomer exclusively. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6693 / 6696
页数:4
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