The selective functionalization of saturated hydrocarbons .10. Aspects of Fe-II based peroxide fragmentation in pyridine solution.

被引：8

作者：

Barton, DHR

Launay, F

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON | 1997年 / 53卷 / 43期

关键词：

D O I：

10.1016/S0040-4020(97)01063-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Haber-Weiss mechanism does not apply to the Fe-II induced fragmentation of primary and secondary hydroperosides in pyridine. However, it does apply to tertiary hydroperoxides. Steric bulk is an important factor in Fe-II induced dialkyl peroxide decomposition in pyridine. On the contrary in tetrahydrofuran a different relatively unhindered electron transfer process predominates where the Fe-II becomes a catalyst. (C) 1997 Elsevier Science Ltd.

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页码：14565 / 14578

页数：14

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