Luminescent gold(I) supermolecules with trithiocyanuric acid. Crystal structure, spectroscopic and photophysical properties

被引：59

作者：

Tzeng, BC

Che, CM

Peng, SM

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a703891g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of an ordered array of Au-6 clusters with trithiocyanuric acid, [(LAu)(AuPPhMe2)(2)](2) (H3L = trithiocyanuric acid), is prepared and characterized by X-ray crystallography; it has a two-dimensional structure via intermolecular Au-I ... Au-I interactions and possesses photoluminescence properties; the ability of trithiocyanuric acid to act as a bridging ligand for molecular assembly of two-dimensional polymeric solids is demonstrated.

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页码：1771 / 1772

页数：2

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