A heterobimetallic rhodium(I)-ruthenium(II) catalyst for the Oppenauer-type oxidation of primary and secondary alcohols under mild conditions

被引：70

作者：

Gauthier, S ^{[1
]}

Scopelliti, R ^{[1
]}

Severin, K ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 16期

关键词：

D O I：

10.1021/om049671m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A heterobimetallic complex, in which a RuCl2(acetone) (PPh3)(2) fragment is connected via three chloro bridges to a (eta(4)-C4Ph4CO)RhCl fragment, has been identified as a potent catalyst precursor for the Oppenauer-type oxidation of alcohols. With 0.1-0.5 mol % of this complex and K2CO3 as the cocatalyst, it is possible to oxidize secondary and primary alcohols at room temperature using acetone as the solvent and oxidation agent.

引用

页码：3769 / 3771

页数：3

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