Sucrose esterification under Mitsunobu conditions:: evidence for the formation of 6-0-acyl-3',6'-anhydrosucrose besides mono and diesters of fatty acids

被引：29

作者：

Molinier, V ^{[1
]}

Fitremann, J ^{[1
]}

Bouchu, A ^{[1
]}

Queneau, Y ^{[1
]}

机构：

[1] Inst Natl Sci Appl, CNRS, Chim Organ Lab, UMR 5181, F-69621 Villeurbanne, France

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 11期

关键词：

D O I：

10.1016/j.tetasy.2004.04.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of sucrose monoesters and homogeneous or mixed diesters, which have various chain lengths and saturation levels, were prepared under Mitsunobu conditions with good regioselectivity. Among the anhydro derivatives arising from competitive intramotecular etherification, 3,6'-anhydrosucrose 6-O-monoesters, which have never been reported, were identified. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：1753 / 1762

页数：10

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