Large area electrodeposition of Cu(In,Ga)Se2

被引:51
作者
Kampmann, A [1 ]
Sittinger, V [1 ]
Rechid, J [1 ]
Reineke-Koch, R [1 ]
机构
[1] Inst Solar Energieforsch GMBH, D-30165 Hannover, Germany
关键词
electrodeposition; In2Se3; CIGS; superstrate cell;
D O I
10.1016/S0040-6090(99)00863-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The feasibility of large area electrodeposition of copper indium diselenide (CIS) for solar cell applications is investigated. CIS is deposited onto 80 cm(2) of ITO/In2Se3 and Mo substrates. The uniformity of the properties of the deposits is investigated by optical transmission and photocurrent spectra. Results for a cadmium free superstrate cell with a ITO/In2Se3/CIS/Au structure are presented, in which the buffer layer and the absorber layer were successively electrodeposited. The maximum selenisation temperature must be limited to 325 degrees C to avoid pn-junction destruction which is probably caused by interdiffusion processes. The best substrate cell with a Mo/CIS/CdS/ZnO structure yielded a preliminary efficiency of 4.8%. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:309 / 313
页数:5
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