Hydrothermal synthesis, crystal structures of two new transition metal coordination chain polymers with mixed ligands

被引：30

作者：

He, X ^{[1
]}

Lu, CZ ^{[1
]}

Yan, Y ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 07期

基金：

中国国家自然科学基金;

关键词：

transition metal complex; mixed ligands; photoluminescence; NLO;

D O I：

10.1016/j.inoche.2004.04.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reactions of fumaric acid, 1,10-phenanthroline or 2,2'-bipyridine and transition metal cations gave rise to two complexes, [Zn(Hmal)(1,10-phen)(H2O)](n) (1) and [Cu(Hmal)(2,2'-bipy)](n).3nH(2)O (2) (malic acid=H(3)mal). The photoluminescence spectrum and the interesting second-order non-linear optical (NLO) property for compound 1 have been studied. (C) 2004 Elsevier B.V. All rights reserved.

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收藏

页码：851 / 853

页数：3

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