Oxime palladacycles revisited:: Stone-stable complexes nonetheless very active catalysts

被引：108

作者：

Alacid, Emilio

Alonso, Diego A.

Botella, Luis

Najera, Carmen

Pacheco, M. Carmen

机构：

[1] Univ Alicante, Dept Quim Organ, Fac Ciencias, E-03080 Alicante, Spain

[2] Univ Alicante, Inst Sintesis Organ, Fac Ciencias, E-03080 Alicante, Spain

来源：

CHEMICAL RECORD | 2006年 / 6卷 / 03期

关键词：

palladacycle; oxime; nanoparticles; catalysis; cross coupling;

D O I：

10.1002/tcr.20077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Our review critically presents the main achievements, advantages, and limitations of oxime palladacycles as high-turnover catalysts for Heck, as well as homo- and cross-coupling reactions such as Suzuki-Miyaura, Stille, Ullmann-type, Cassar-Heck-Sonogashira, sila-Sonogashira, Glaser-type, Hiyama, and alkoxycarbonylation reactions. New developments in this area are reviewed from a mechanistic and synthetic point of view. The role of oxime palladacycles as a source of highly active zero-valent palladium species is also discussed. (c) 2006 The Japan Chemical journal Forum and Wiley Periodicals, Inc.

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页码：117 / 132

页数：16

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