Synthetic methods applied to the detection of chemical warfare nerve agents

被引：42

作者：

Giordano, Braden C. ^{[1
]}

Collins, Greg E. ^{[1
]}

机构：

[1] USN, Res Lab, Div Chem, Washington, DC 20375 USA

来源：

CURRENT ORGANIC CHEMISTRY | 2007年 / 11卷 / 03期

关键词：

D O I：

10.2174/138527207779940883

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent events as they relate to the war on terror make it abundantly clear that the rapid detection of chemical warfare nerve agents is essential. While the detection of these agents clearly falls into the purview of the analytical chemist, the importance or the organic chemist in the development of new techniques or approaches remains intact. This review serves to introduce the reader to a number of methods for detecting nerve agents with a focus on those techniques which rely oil synthetic chemistry to improve overall performance with respect to selectivity, sensitivity and analysis time.

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页码：255 / 265

页数：11

相关论文

共 60 条

[1] Electrochemical and optical bioassays of nerve agents based on the organophosphorus-hydrolase mediated growth of cupric ferrocyanide nanoparticles [J].

Arribas, AS ;

Vázquez, T ;

Wang, J ;

Mulchandani, A ;

Chen, W .

ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (12) :1371-1374

[2] ORTHO-PHTHALALDEHYDE - FLUOROGENIC DETECTION OF PRIMARY AMINES IN PICOMOLE RANGE - COMPARISON WITH FLUORESCAMINE AND NINHYDRIN [J].

BENSON, JR ;

HARE, PE .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1975, 72 (02) :619-622

[3] 2,2-Bis(3-allyl-4-hydroxyphenyl)hexafluoropropane and fluorosiloxane as coating materials for nerve agent sensors [J].

Bhadury, PS ;

Dubey, V ;

Singh, S ;

Saxena, C .

JOURNAL OF FLUORINE CHEMISTRY, 2005, 126 (08) :1252-1256

[4] Derivatisation reactions in the chromatographic analysis of chemical warfare agents and their degradation products [J].

Black, RM ;

Muir, B .

JOURNAL OF CHROMATOGRAPHY A, 2003, 1000 (1-2) :253-281

[5] Synthesis of CuII-complexed polymers and use as catalysts in the hydrolytic decontamination of Sarin nerve agent [J].

Blacker, NC ;

Findlay, PH ;

Sherrington, DC .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2001, 12 (3-4) :183-196

[6]

Boyd JW, 2004, J HOPKINS APL TECH D, V25, P44

[7] Classification of chemical warfare agents using thick film gas sensor array [J].

Choi, NJ ;

Kwak, JH ;

Lim, YT ;

Bahn, TH ;

Yun, KY ;

Kim, JC ;

Huh, JS ;

Lee, DD .

SENSORS AND ACTUATORS B-CHEMICAL, 2005, 108 (1-2) :298-304

[8] Separation of thiol and cyanide hydrolysis products of chemical warfare agents by capillary electrophoresis [J].

Copper, CL ;

Collins, GE .

ELECTROPHORESIS, 2004, 25 (06) :897-902

[9] Determination of organophosphate pesticides at a carbon nanotube/organophosphorus hydrolase electrochemical biosensor [J].

Deo, RP ;

Wang, J ;

Block, I ;

Mulchandani, A ;

Joshi, KA ;

Trojanowicz, M ;

Scholz, F ;

Chen, W ;

Lin, YH .

ANALYTICA CHIMICA ACTA, 2005, 530 (02) :185-189

[10] REACTION FOR COLORIMETRIC ESTIMATION OF SOME PHOSPHORUS COMPOUNDS [J].

GEHAUF, B ;

EPSTEIN, J ;

WILSON, GB ;

WITTEN, B ;

SASS, S ;

BAUER, VE ;

RUEGGEBERG, WHC .

ANALYTICAL CHEMISTRY, 1957, 29 (02) :278-281

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