Layered double hydroxides containing chiral organic guests: Synthesis, characterization and application for asymmetric C-C bond-forming reactions

被引：53

作者：

Choudary, BM ^{[1
]}

Kavita, B ^{[1
]}

Chowdari, NS ^{[1
]}

Sreedhar, B ^{[1
]}

Kantam, ML ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

CATALYSIS LETTERS | 2002年 / 78卷 / 1-4期

关键词：

C-C bond formation; asymmetric catalysis; immobilization; LDH-proline and LDH-BINOL;

D O I：

10.1023/A:1014941625580

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We designed and developed two heterogeneous enantioselective catalysts, LDH-proline and LDH-BINOL, by incorporating chiral organic molecules viz., L-proline and S-BINOL, into layered double hydroxides (LDHs). These catalysts are characterized by IR, UV/vis and TGA analysis. These organo-LDHs have been successfully employed for various asymmetric C-C bond-forming transformations, and the products are obtained with good to excellent yields albeit low enantiomeric excess.

引用

页码：373 / 377

页数：5

共 18 条

[1] CATALYTIC ENANTIOSELECTIVE C-C COUPLING - ALLYL TRANSFER AND MUKAIYAMA ALDOL REACTION [J].

BACH, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (04) :417-419

[2]

Baiker A, 1996, STUD SURF SCI CATAL, V101, P51

[3]

BLASER HU, 1991, STUD SURF SCI CATAL, V67, P147, DOI 10.1016/S0167-2991(08)61934-5

[4] THERMAL-BEHAVIOR OF HYDROTALCITE AND OF ANION-EXCHANGED FORMS OF HYDROTALCITE [J].

BRINDLEY, GW ;

KIKKAWA, S .

CLAYS AND CLAY MINERALS, 1980, 28 (02) :87-91

[5]

Gröger H, 2001, ANGEW CHEM INT EDIT, V40, P529

[6] ASYMMETRIC CARBON-CARBON BOND-FORMING REACTIONS CATALYZED BY CHIRAL SCHIFF BASE-TITANIUM ALKOXIDE COMPLEXES [J].

HAYASHI, M ;

INOUE, T ;

MIYAMOTO, Y ;

OGUNI, N .

TETRAHEDRON, 1994, 50 (15) :4385-4398

[7] THE ENANTIOSELECTIVE HYDROGENATION OF METHYL ACETOACETATE OVER SUPPORTED NICKEL-CATALYSTS .1. THE MODIFICATION PROCEDURE [J].

KEANE, MA ;

WEBB, G .

JOURNAL OF CATALYSIS, 1992, 136 (01) :1-15

[8] INTERCALATION AND EXCHANGE-REACTIONS OF CLAY-MINERALS AND NON-CLAY LAYER COMPOUNDS [J].

LAGALY, G ;

BENEKE, K .

COLLOID AND POLYMER SCIENCE, 1991, 269 (12) :1198-1211

[9]

MENDIBOURE A, 1986, REV CHIM MINER, V23, P819

[10] ANION-EXCHANGE PROPERTIES OF HYDROTALCITE-LIKE COMPOUNDS [J].

MIYATA, S .

CLAYS AND CLAY MINERALS, 1983, 31 (04) :305-311

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