On the O-2 (upsilon')+O-2 (upsilon'') atmospheric reaction: A quasiclassical trajectory study

被引：48

作者：

Varandas, AJC

Wang, W

机构：

[1] Departamento de Química, Universidade de Coimbra

来源：

CHEMICAL PHYSICS | 1997年 / 215卷 / 02期

关键词：

D O I：

10.1016/S0301-0104(96)00344-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report a theoretical study of the title four-atom atmospheric reaction for a wide range of initial vibrational quantum numbers (upsilon', upsilon ''). All calculations have employed the quasiclassical trajectory method, and a realistic potential energy surface obtained by using the double many-body expansion (DMBE) method. The implications of the results on a recently proposed hypothesis to explain the 'ozone deficit' problem are tentatively assessed.

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页码：167 / 182

页数：16

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