Enantioselective synthesis of six membered carbocycles through [4+2] cycloaddition reactions of chiral 2-amino-1,3-butadienes and tungsten vinyl Fischer type carbene complexes

被引：28

作者：

Barluenga, J

Aznar, F

Martin, A

Barluenga, S

机构：

[1] Inst. Univ. Quim. Orgmet. Enrique M., Universidad de Oviedo, 33071 Oviedo, C/ Julián Clavería S/N

来源：

TETRAHEDRON | 1997年 / 53卷 / 27期

关键词：

D O I：

10.1016/S0040-4020(97)00586-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Amino-1,3-butadienes 1 react with carbene complexes 2 to yield, after hydrolysis, cyclohexanone derivatives. The use of chiral enantiomerically pure dienes 19 allow the access to enantio-enriched cycloadduct complexes. (C) 1997 Elsevier Science Ltd.

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收藏

页码：9323 / 9340

页数：18

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