Synthesis and characterization of a quasi-one-coordinate lead cation

被引：71

作者：

Hino, S ^{[1
]}

Brynda, M ^{[1
]}

Phillips, AD ^{[1
]}

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 20期

关键词：

cations; Group; 14; elements; lead; structural elucidation; terphenyl ligands;

D O I：

10.1002/anie.200353365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Easily lead: The demethylation of [PbMe(2,6-Trip2C 6H3)] (Trip = 2,4,6-iPr3C6H 2) with tris(perfluorophenyl)borane in toluene affords [Pb(2,6-Trip2C6H3)·(η2- MeC6H5)][B(Me)(C6F5)3] (see picture), in which the lead center is singly bound to the 2,6-Trip 2C6H3 moiety and also weakly solvated by toluene.

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页码：2655 / 2658

页数：4

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