Preparation, crystal structure analysis, and catalytic application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2

被引：33

作者：

Spielvogel, DJ ^{[1
]}

Davis, WM ^{[1
]}

Buchwald, SL ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 18期

关键词：

D O I：

10.1021/om020164j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The efficient preparation of [(S)-BINAP]Ni-(COD) (1) and [(S)-BINAP]NiBr2 (2) is reported. X-ray crystal structure analysis of these potential precatalysts provides the first structural insights into the nickel-BINAP system at both the 0 and +2 oxidation states.

引用

页码：3833 / 3836

页数：4

共 29 条

[1] Convenient and direct preparation of tertiary phosphines via nickel-catalysed cross-coupling
Ager, DJ
East, MB
Eisenstadt, A
Laneman, SA
[J]. CHEMICAL COMMUNICATIONS, 1997, (24) : 2359 - 2360
[2] Enantioselective isomerization of allylamine to enamine: practical asymmetric synthesis of (-)-menthol by Rh-BINAP catalysts
Akutagawa, S
[J]. TOPICS IN CATALYSIS, 1997, 4 (3-4) : 271 - 274
[3] ASYMMETRIC-SYNTHESIS BY METAL BINAP CATALYSTS
AKUTAGAWA, S
[J]. APPLIED CATALYSIS A-GENERAL, 1995, 128 (02) : 171 - 207
[4] Suggested modifications to a distillation-free solvent purification system
Alaimo, PJ
Peters, DW
Arnold, J
Bergman, RG
[J]. JOURNAL OF CHEMICAL EDUCATION, 2001, 78 (01) : 64 - 64
[5] SYNTHESIS OF CHIRAL 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) VIA A NOVEL NICKEL-CATALYZED PHOSPHINE INSERTION
CAI, DW
PAYACK, JF
BENDER, DR
HUGHES, DL
VERHOEVEN, TR
REIDER, PJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (23) : 7180 - 7181
[6] Cai DW, 1999, ORG SYNTH, V76, P6
[7] The bite angle makes the difference: a practical ligand parameter for diphosphine ligands
Dierkes, P
van Leeuwen, PWNM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (10): : 1519 - 1529
[8] Highly active and selective catalysts for the formation of α-aryl ketones
Fox, JM
Huang, XH
Chieffi, A
Buchwald, SL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) : 1360 - 1370
[9] GAMLICH V, 1979, HELV CHIM ACTA, V62, P1016
[10] Counterions of BINAP-Pt(II) and -Pd(II) complexes: Novel catalysts for highly enantioselective Diels-Alder reaction
Ghosh, AK
Matsuda, H
[J]. ORGANIC LETTERS, 1999, 1 (13) : 2157 - 2159

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