Luminescence of salts and copolymers containing the (MoII6Cl8)4+ cluster

被引：12

作者：

Adamenko, OA ^{[1
]}

Loukova, GV ^{[1
]}

Smirnov, VA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

molybdenum clusters; cluster-containing polymer; charge transfer; luminescence;

D O I：

10.1023/A:1019609601612

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photophysical properties (absorption, emission) of the (Bu4N)(2)[((Mo6Cl8)-Cl-II)L-6] (L=CF3COO-, CH2=CHCOO-) cluster salts and (Bu4N)(2)[((Mo6Cl8)-Cl-II)(CF3COO)(6-n)]-polyacrylic acid copolymers were studied. Both the cluster-containing monomers and corresponding copolymers phosphoresce intensely (tausimilar to0.2-0.4 ms at 77-300 K).

引用

页码：994 / 997

页数：4

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