The reactions of 2-(chloroseleno)benzoyl chloride with nucleophiles

被引：26

作者：

Osajda, M ^{[1
]}

Mlochowski, J ^{[1
]}

机构：

[1] Wroclaw Univ Technol, Inst Organ Chem Biochem & Biotechnol, PL-50375 Wroclaw, Poland

来源：

TETRAHEDRON | 2002年 / 58卷 / 37期

关键词：

nucleophiles; acylation; selenium halogen compounds; selenium heterocycles;

D O I：

10.1016/S0040-4020(02)00789-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The reactions of 2-(chloroseleno)benzoyl chloride with N, O and S nucleophiles such as alkanols, aminoalkanols, phenols, thiols, aminothiols and thiophenols have been investigated. It was found that the most reactive was a primary amino group which simultaneously underwent selenenylation-acylation. Less reactive hydroxy and thiol groups were selenenylated and/or acylated depending on the structure of the substrate and reaction conditions. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：7531 / 7537

页数：7

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