Interaction between tetrathiafulvalene carboxylic acid and ytterbium D03A: solution state self-assembly of a ternary complex which is luminescent in the near IR

被引：89

作者：

Faulkner, S ^{[1
]}

Burton-Pye, BP ^{[1
]}

Khan, T ^{[1
]}

Martin, LR ^{[1
]}

Wray, SD ^{[1
]}

Skabara, PJ ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 16期

关键词：

D O I：

10.1039/b204218e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrathiafulvalene carboxylate associates with the charge neutral complex, Yb.DO3A, in methanolic solution to give rise to a novel ternary species; the tetrathiafulvalene unit transfers energy to the lanthanide, causing luminescence from the Yb metal, indicating for the first time that an electron donor chromophore can act as an efficient sensitiser in a self-assembled system containing a lanthanide acceptor.

引用

页码：1668 / 1669

页数：2

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