Cycloaddition reactions of trimethylenemethane radical cation generated from methylenecyclopropanone thioacetal

被引：38

作者：

Nakamura, M ^{[1
]}

Toganoh, M ^{[1
]}

Ohara, H ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 01期

关键词：

D O I：

10.1021/ol9900055

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new trimethylenemethane precursor, methylenecyclopropanone thioacetal 2, was synthesized, Trimethylenemethane species generated from 2 showed broad reactivities toward electron-deficient and electron-rich olefins under thermal or photochemical conditions.

引用

页码：7 / 9

页数：3

共 11 条

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