Unexpected formation of 1,3-diols from unsaturated chromium Fischer carbene complexes and borane

被引：7

作者：

Barluenga, J

Granados, A

Rodriguez, F

Vadecard, J

Fananas, FJ

机构：

[1] Inst. Univ. Quim. Orgmet. Enrique M., Unidad Asociada al C.S.I.C., Universidad de Oviedo, 33071 Oviedo, Julián Clavería

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(97)01478-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha,beta-unsaturated Fischer carbene complexes of chromium 1 react with borane-dimethyl sulfide complex to give, after oxidation with hydrogen peroxide and sodium hydroxide, 1,3-diols 2 and variable amounts of alcohols 3. The same procedure applied to alkynyl chromium carbene complex 4 leads to 3-hydroxyketone 5. (C) 1997 Elsevier Science Ltd.

引用

页码：6465 / 6466

页数：2

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