Core-shell latex containing fluorinated polymer rich in shell

被引:64
作者
Cheng, SY [1 ]
Chen, YJ [1 ]
Chen, ZG [1 ]
机构
[1] Hubei Univ, Dept Chem, Wuhan 430062, Peoples R China
关键词
fluoropolymer; core-shell acrylate latex; dynamic contact angle;
D O I
10.1002/app.10622
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Core-shell latex with polyacrylate rich in core and fluoropolymer rich in shell was prepared by semicontinuous emulsion polymerization in the presence of mixed emulsifiers. The solids content of the latex was about 25 wt %. The polymerization conditions for the latex were discussed. The morphology of latex particles was characterized by transmission electron microscopy and the surface properties were determined by the Wilhelmy method. (C) 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1147-1153,2002.
引用
收藏
页码:1147 / 1153
页数:7
相关论文
共 17 条
[11]  
2-F
[12]   Synthesis of fluorine-containing graft copolymers of poly(perfluoroalkylethyl methacrylate)-g-poly(methyl methacrylate) by the macromonomer technique and emulsion copolymerization method [J].
Park, IJ ;
Lee, SB ;
Choi, CK .
POLYMER, 1997, 38 (10) :2523-2527
[13]   Surface properties of the fluorine-containing graft copolymer of poly((perfluoroalkyl)ethyl methacrylate)-g-poly(methyl methacrylate) [J].
Park, IJ ;
Lee, SB ;
Choi, CK .
MACROMOLECULES, 1998, 31 (21) :7555-7558
[14]   Surface properties and structure of poly(perfluoroalkylethyl methacrylate) [J].
Park, IJ ;
Lee, SB ;
Choi, CK ;
Kim, KJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 181 (01) :284-288
[15]  
Tirelli N, 1998, MACROMOL CHEM PHYSIC, V199, P2425, DOI 10.1002/(SICI)1521-3935(19981101)199:11<2425::AID-MACP2425>3.3.CO
[16]  
2-L
[17]   SURFACE MOBILITY AND STRUCTURAL TRANSITIONS OF POLY(NORMAL-ALKYL METHACRYLATES) PROBED BY DYNAMIC CONTACT-ANGLE MEASUREMENTS [J].
VANDAMME, HS ;
HOGT, AH ;
FEIJEN, J .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 114 (01) :167-172