New synthesis of 2-[1,3-dithiol-2-ylidene]-5,6-dihydro-1,3-dithiolo[4,5-b][1,4]dithiins with formyl group on fused benzene, [1,4]dithiin, or thiophene ring

被引：18

作者：

Ishikawa, Y

Miyamoto, T

Yoshida, A

Kawada, Y

Nakazaki, J

Izuoka, A

Sugawara, T

机构：

[1] Ibaraki Univ, Fac Sci, Dept Chem, Mito, Ibaraki 3108512, Japan

[2] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 50期

关键词：

thiafulvalenes; aldehydes; benzenes; thiophenes;

D O I：

10.1016/S0040-4039(99)01851-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

As novel TTF-based annelated donors, 2-[1,3-dithiol-2-ylidene]-5,6-dihydro-1,3-dithiolo[4,5-b][1,4]dithiins with a formyl group on fused benzene, [1,4]-dithiin, or thiophene ring, respectively, were prepared using Diels-Alder or an intramolecular aldol reaction. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：8819 / 8822

页数：4

相关论文

共 22 条

[1] OLIGOMERIC TETRATHIAFULVALENES - EXTENDED DONORS FOR INCREASING THE DIMENSIONALITY OF ELECTRICAL-CONDUCTION [J].

ADAM, M ;

MULLEN, K .

ADVANCED MATERIALS, 1994, 6 (06) :439-459

[2] GENERAL SYNTHESIS OF 1,3-DITHIOL-2-ONES [J].

BHATTACHARYA, AK ;

HORTMANN, AG .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (01) :95-97

[3] STUDIES OF STABLE FREE RADICALS .3. A 1,3-DIOXY-2-IMIDAZOLIDONE ZWITTERION AND ITS STABLE NITRONYL NITROXIDE RADICAL ANION [J].

BOOCOCK, DGB ;

ULLMAN, EF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (24) :6873-&

[4]

BRICE MR, 1991, CHEM SOC REV, V20, P355

[5] ORGANIC METALS - SYSTEMATIC MOLECULAR MODIFICATIONS OF HEXAMETHYLENETETRAHETEROFULVALENE DONORS [J].

ENGLER, EM ;

PATEL, VV ;

ANDERSEN, JR ;

SCHUMAKER, RR ;

FUKUSHIMA, AA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (12) :3769-3776

[6]

GROSSEL MC, 1994, CONTEMP ORG SYNTH, P367

[7] Synthesis and properties of bis(ethyleneseleno)tetrathiafulvalene (BES-TTF) and diselenolotetrathiafulvalene (DS-TTF) as novel electron donors [J].

Jigami, T ;

Takimiya, K ;

Aso, Y ;

Otsubo, T .

CHEMISTRY LETTERS, 1997, (11) :1091-1092

[8] TETRATHIAFULVALENES AS BUILDING-BLOCKS IN SUPRAMOLECULAR CHEMISTRY [J].

JORGENSEN, T ;

HANSEN, TK ;

BECHER, J .

CHEMICAL SOCIETY REVIEWS, 1994, 23 (01) :41-51

[9]

KRIEF A, 1986, TETRAHEDRON, V42, P1209

[10] INTRAMOLECULAR EXCHANGE INTERACTION IN A NOVEL CROSS-CONJUGATED SPIN SYSTEM COMPOSED OF PI-ION RADICAL AND NITRONYL NITROXIDE [J].

KUMAI, R ;

MATSUSHITA, MM ;

IZUOKA, A ;

SUGAWARA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) :4523-4524