Synthesis and spectroscopic and electrochemical properties of new ligand 1,3-bis(4′-methyl-2,2′-bipyridin-4-yl)propan-2-one and its ruthenium(II) complexes

被引：1

作者：

Bian, Zhao-Yong ^{[1
,2
]}

Furue, Masaoki ^{[2
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

[2] Kochi Univ Technol, Dept Environm Syst Engn, Kochi 7828502, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Mono- and dinuclear Ru(II) complexes; Carbonyl group; NMR; Spectroscopic properties; Electrochemistry; POLYPYRIDINE COMPLEXES; ELECTRON-TRANSFER; 2,2'-BIPYRIDINE; LUMINESCENT; BIPYRIDINE;

D O I：

10.1016/j.inoche.2008.10.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new bridging ligand, 1,3-bis(4'-methyl-2,2'-bipyridin-4-yl)propan-2-one (L) and its mono- and dinuclear Ru(II) complexes have been synthesized and characterized. The carbonyl group in L keeps its character and does not affect the Ru(II) moieties. In addition, the two Ru(II) terminuses of the dinuclear complex have no interaction through the bridging linkage. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：32 / 34

页数：3

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