A σ4, λ5-phosphinine palladium complex:: a new type of phosphorus ligand and catalyst.: Application to the Pd-catalyzed formation of arylboronic esters

被引：75

作者：

Doux, M ^{[1
]}

Mézailles, N ^{[1
]}

Melaimi, M ^{[1
]}

Ricard, L ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, UMR 7653, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 15期

关键词：

D O I：

10.1039/b203550b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A palladium(II) complex of a S-P-S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76500).

引用

页码：1566 / 1567

页数：2

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