Self-organization of oligomeric helical stacks controlled by substrate binding in a tobacco mosaic virus like self-assembly process

被引：48

作者：

Petitjean, A

Nierengarten, H

van Dorsselaer, A

Lehn, JM

机构：

[1] ISIS, Lab Chim Supramol, F-67083 Strasbourg, France

[2] ECPM, Lab Spectrometrie Masse Bioorgan, F-67088 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 28期

关键词：

amines; helical structures; N ligands; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200353492

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly with a twist: Linear polyammonium threads are templates in the organization of helical heterocyclic building blocks to form stacks of helices as a model for the Tobacco Mosaic Virus. The length of the cationic substrate and the spacing of the positive charges within the thread dictate the size of the final self-organized supramolecular architecture (see picture).

引用

页码：3695 / 3699

页数：5

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