Two heteroleptic cobalt(III) cyclopentadienyl/dithiolene complexes

被引：20

作者：

Fourmigue, M

Perrocheau, V

机构：

[1] Inst. des Matériaux de Nantes, UMR 110 CNRS, Université de Nantes, 44322 Nantes Cedex 03

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270197005544

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure determinations of (eta(5)-cyclopentadienyl)(4,5-dimercapto-1,3-dithiole-2-thionato)cobalt(III), [Co(C5H5)(C3S5)], and (4,5-dimercapto-1,3-dithiole-2-thionato)(eta(5)-pentamethylcyclopentadienyl)cobalt(III), [Co(C10H15)(C3S5)], show that Cp* substitution does not significantly modify the geometric features of these complexes, which are characterized by a perpendicular arrangement of the planar Cp or Cp* and (CoS2C2) moieties.

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页码：1213 / 1215

页数：3

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