Transfer hydrodehalogenation of organic halides catalyzed by water soluble ruthenium(II) phosphine complexes

被引：29

作者：

Benyei, AC

Lehel, S

Joo, F

机构：

[1] Institute of Physical Chemistry, Lajos Kossuth University, H-4010 Debrecen

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 116卷 / 03期

基金：

匈牙利科学研究基金会;

关键词：

hydrodehalogenation; hydrogen transfer reaction; sodium formate; ruthenium; water soluble phosphines;

D O I：

10.1016/S1381-1169(96)00369-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

C-X bonds in carbon tetrachloride, chloroform and 1-hexyl halogenides were transformed into C-H bonds in a transfer hydrodehalogenation reaction catalyzed by water soluble ruthenium(II) phosphine complexes. A turnover frequency of up to 1000 h(-1) can be achieved when an aqueous solution of sodium formate is the hydrogen donor and RuCl2(TPPMS)(2) (1) the catalyst (TPPMS = m-sulfophenyl diphenylphosphine sodium salt).

引用

页码：349 / 354

页数：6

共 45 条

[1] THE RELATIVE AFFINITIES OF CO-ORDINATING ATOMS FOR SILVER ION .2. NITROGEN, PHOSPHORUS, AND ARSENIC
AHRLAND, S
CHATT, J
DAVIES, NR
WILLIAMS, AA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1958, (JAN): : 276 - 288
[2] HOMOGENEOUS METAL-CATALYZED HYDROGENOLYSIS OF C-F BONDS
AIZENBERG, M
MILSTEIN, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (33) : 8674 - 8675
[3] THE INVENTION OF RADICAL REACTIONS .32. RADICAL DEOXYGENATIONS, DEHALOGENATIONS, AND DEAMINATIONS WITH DIALKYL PHOSPHITES AND HYPOPHOSPHOROUS ACID AS HYDROGEN SOURCES
BARTON, DHR
JANG, DO
JASZBERENYI, JC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (24) : 6838 - 6842
[4] ORGANOMETALLIC CATALYSIS IN AQUEOUS-SOLUTIONS - THE BIPHASIC TRANSFER HYDROGENATION OF ALDEHYDES CATALYZED BY WATER-SOLUBLE PHOSPHINE COMPLEXES OF RUTHENIUM, RHODIUM AND IRIDIUM
BENYEI, A
JOO, F
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1990, 58 (02): : 151 - 163
[5] A MODIFIED SYNTHESIS OF RUTHENIUM(II) HEXAAQUA SALTS
BERNHARD, P
BINER, M
LUDI, A
[J]. POLYHEDRON, 1990, 9 (08) : 1095 - 1097
[6] CHALONER PA, 1994, CATALYSIS METAL COMP
[7] DAIGLE DJ, 1974, J HETEROCYCLIC CHEM, V17, P407
[8] WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .4. CATALYTIC-HYDROGENATION OF ALDEHYDES IN AN AQUEOUS 2-PHASE SOLVENT SYSTEM USING A 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEX OF RUTHENIUM
DARENSBOURG, DJ
JOO, F
KANNISTO, M
KATHO, A
REIBENSPIES, JH
DAIGLE, DJ
[J]. INORGANIC CHEMISTRY, 1994, 33 (02) : 200 - 208
[9] INTERCONVERSION OF CHLOROFLUOROCARBONS IN PLASMAS
DEAM, RT
DAYAL, AR
MCALLISTER, T
MUNDY, AE
WESTERN, RJ
BESLEY, LM
FARMER, AJD
HORRIGAN, EC
MURPHY, AB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (03) : 347 - 348
[10] THERMAL GAS-PHASE HYDRODEHALOGENATION OF BROMOCHLORODIFLUOROMETHANE
DELIJSER, HJP
LOUW, R
MULDER, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (01): : 139 - 145

← 1 2 3 4 5 →