Equilibrium data and thermodynamic modelling of isopentane and 2,2-dimethylpentane hydrates

被引：31

作者：

Ostergaard, KK ^{[1
]}

Tohidi, B ^{[1
]}

Danesh, A ^{[1
]}

Burgass, RW ^{[1
]}

Todd, AC ^{[1
]}

机构：

[1] Heriot Watt Univ, Dept Petr Engn, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

FLUID PHASE EQUILIBRIA | 2000年 / 169卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

experimental; data; hydrates; model; alkanes;

D O I：

10.1016/S0378-3812(00)00309-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Experimental hydrate equilibrium data and thermodynamic modelling of isopentane and 2,2-dimethylpentane (2,2-DMP) are presented. Both compounds are reported to form structure-H gas hydrates in the presence of a help gas. Hydrate dissociation data for isopentane and 2,2-DMP in their binaries and ternaries with methane and/or nitrogen are measured and successfully modelled using an equation of state-based thermodynamic model. Indication of a change in the stable hydrate structure (structure-H to structure-I) for isopentane and 2,2-DMP in their binaries with methane at higher temperatures is also discussed. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：101 / 115

页数：15

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