Water? What's so special about it?

被引:136
作者
Finney, JL [1 ]
机构
[1] UCL, Dept Phys & Astron, London WC1E 6BT, England
关键词
water molecule; water-water interactions; ices; liquid water; anomalous properties;
D O I
10.1098/rstb.2004.1495
中图分类号
Q [生物科学];
学科分类号
07 ; 0710 ; 09 ;
摘要
What is so special about water? Why does it have the properties it has, and how might these reasons be relevant to its apparent biological importance? By exploring the structure and dynamics of water, from the isolated molecule and its interactions, through its many crystalline phases and to its so-called anomalous liquid phase, some of its apparently unusual behaviour is rationalized. The way in which it interacts with some relatively simple interfaces is also discussed. As a result of this exploration, a checklist of possible molecular-level reasons for its biological importance is devised.
引用
收藏
页码:1145 / 1163
页数:19
相关论文
共 49 条
[1]   THE GROTTHUSS MECHANISM [J].
AGMON, N .
CHEMICAL PHYSICS LETTERS, 1995, 244 (5-6) :456-462
[2]  
ALL P, 2003, NATURE, V423, P25
[3]  
[Anonymous], 1806, ANN CHIM-ROME
[4]   ELECTRON DENSITY DISTRIBUTIONS IN HYDRIDE MOLECULES .1. WATER MOLECULE [J].
BADER, RFW ;
JONES, GA .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1963, 41 (03) :586-&
[5]  
BENNAIM A, 1972, STRUCTURE TRANSPORT, P295
[6]   A theory of water and ionic solution, with particular reference to hydrogen and hydroxyl ions [J].
Bernal, JD ;
Fowler, RH .
JOURNAL OF CHEMICAL PHYSICS, 1933, 1 (08) :515-548
[8]   HIGH-RESOLUTION NEUTRON STUDY OF VITAMIN-B-12 COENZYME AT 15-K - SOLVENT STRUCTURE [J].
BOUQUIERE, JP ;
FINNEY, JL ;
SAVAGE, HFJ .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1994, 50 :566-578
[9]   Hydrophobic hydration and the formation of a clathrate hydrate [J].
Bowron, DT ;
Filipponi, A ;
Roberts, MA ;
Finney, JL .
PHYSICAL REVIEW LETTERS, 1998, 81 (19) :4164-4167
[10]  
BUCKINGHAM AD, 1986, WATER AQUEOUS SOLUTI, P1