A novel asymmetric benzoin reaction catalyzed by a chiral triazolium salt - Preliminary Communication

被引：199

作者：

Enders, D ^{[1
]}

Breuer, K ^{[1
]}

Teles, JH ^{[1
]}

机构：

[1] BASF AG,AMMONIAKLAB,D-67056 LUDWIGSHAFEN,GERMANY

来源：

HELVETICA CHIMICA ACTA | 1996年 / 79卷 / 04期

关键词：

D O I：

10.1002/hlca.19960790427

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using the chiral triazolium salt 1 as catalyst, a novel asymmetric variant of the benzoin reaction is reported. For the first time, the scope of the method is extended to a broader range of aromatic aldehydes 2, affording the acyloins 3a-h in yields of 22-72% and enantiomeric excesses up to 86%.

引用

页码：1217 / 1221

页数：5

共 26 条

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ENDERS, D
BREUER, K
RAABE, G
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MELDER, JP
EBEL, K
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