Ultralong single-crystal TiO2-B nanowires:: Synthesis and electrochemical measurements

被引：48

作者：

Wei, Mingdeng

Qi, Zhi-mei

Ichihara, Masaki

Honma, Itaru

Zhou, Haoshen ^{[1
]}

机构：

[1] AIST, Energy Technol Res Inst, Ibaraki 3058568, Japan

[2] PRESTO, Light & Control Res Grp, Japan Sci & Technol Grp, Kawagoe, Saitama 3320012, Japan

[3] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

[4] AIST, Energy Technol Res Inst, Ibaraki 3058568, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2006年 / 424卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2006.04.066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, ultralong single-crystal TiO2-B nanowires were successfully synthesized starting from Ti2O3 or TiO powder by the hydrothermal process and post-treatments. The diameters of nanowires are ca. similar to 50 nm and the length up to hundreds of micrometers. Formation of the crystallized TiO2-B in the ultralong nanowires was confirmed by X-ray diffraction and transmission electron microscopy measurements. Electrochemical measurements have indicated that the electrode material made of TiO2-B nanowires shows irreversible intercalation/deintercalation of lithium ions into/out of the matrix and tends to loss active with increasing cycling. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：316 / 320

页数：5

共 33 条

[1] Formation of titania nanotubes with high photo-catalytic activity [J].