Highly transparent and flexible triboelectric nanogenerators: performance improvements and fundamental mechanisms

被引:138
作者
Fan, Feng Ru [1 ,2 ]
Luo, Jianjun [1 ]
Tang, Wei [1 ]
Li, Chaoyu [2 ]
Zhang, Cuiping [1 ]
Tian, Zhongqun [2 ]
Wang, Zhong Lin [1 ,3 ]
机构
[1] Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
[2] Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat, Xiamen 361005, Peoples R China
[3] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA
关键词
CONTACT ELECTRIFICATION; IONIC ELECTRETS; GENERATOR; POLY(DIMETHYLSILOXANE); ELECTRONICS; NANOSENSOR; SURFACES; SENSORS; ARRAYS; CHARGE;
D O I
10.1039/c4ta02747g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transparent, flexible and highly efficient power sources are essential components of mobile electronics and optoelectronic devices. Here, based on the first generation of the transparent triboelectric nano-generator (TENG), we demonstrate a simple and innovative design that can simultaneously improve the output performance and transmittance of the TENG. The improved TENG gives a maximum output up to 200 V and 7 mu A at a current density of similar to 0.78 mu A cm(-2). The TENG shows a high transmittance of similar to 78%. To deeply understand the nature of the triboelectric effect, we investigated the influence of the UV-ozone treatment, surface properties, and surrounding environment on the output performance. Integrating the characterization results, we conclude that the tribocharge generation of the PDMS surface is probably due to the bond breaking of Si-O-Si groups, and is closely related to the surface properties and surrounding environment.
引用
收藏
页码:13219 / 13225
页数:7
相关论文
共 34 条
[1]   What Really Drives Chemical Reactions on Contact Charged Surfaces? [J].
Baytekin, Bilge ;
Baytekin, H. Tarik ;
Grzybowski, Bartosz A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (17) :7223-7226
[2]   The Mosaic of Surface Charge in Contact Electrification [J].
Baytekin, H. T. ;
Patashinski, A. Z. ;
Branicki, M. ;
Baytekin, B. ;
Soh, S. ;
Grzybowski, B. A. .
SCIENCE, 2011, 333 (6040) :308-312
[3]   Control of Surface Charges by Radicals as a Principle of Antistatic Polymers Protecting Electronic Circuitry [J].
Baytekin, H. Tarik ;
Baytekin, Bilge ;
Hermans, Thomas M. ;
Kowalczyk, Bartlomiej ;
Grzybowski, Bartosz A. .
SCIENCE, 2013, 341 (6152) :1368-1371
[4]   Material Transfer and Polarity Reversal in Contact Charging [J].
Baytekin, H. Tarik ;
Baytekin, Bilge ;
Incorvati, Jared T. ;
Grzybowski, Bartosz A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (20) :4843-4847
[5]   Flexible triboelectric generator! [J].
Fan, Feng-Ru ;
Tian, Zhong-Qun ;
Wang, Zhong Lin .
NANO ENERGY, 2012, 1 (02) :328-334
[6]   Transparent Triboelectric Nanogenerators and Self-Powered Pressure Sensors Based on Micropatterned Plastic Films [J].
Fan, Feng-Ru ;
Lin, Long ;
Zhu, Guang ;
Wu, Wenzhuo ;
Zhang, Rui ;
Wang, Zhong Lin .
NANO LETTERS, 2012, 12 (06) :3109-3114
[7]   Transparent conducting oxides [J].
Ginley, DS ;
Bright, C .
MRS BULLETIN, 2000, 25 (08) :15-18
[8]   Nanoscale hydrophobic recovery:: A chemical force microscopy study of UV/ozone-treated cross-linked poly(dimethylsiloxane) [J].
Hillborg, H ;
Tomczak, N ;
Olàh, A ;
Schönherr, H ;
Vancso, GJ .
LANGMUIR, 2004, 20 (03) :785-794
[9]   Vibrational spectroscopic analysis of silicones:: A Fourier transform-Raman and inelastic neutron scattering investigation [J].
Jayes, L ;
Hard, AP ;
Séné, C ;
Parker, SF ;
Jayasooriya, UA .
ANALYTICAL CHEMISTRY, 2003, 75 (04) :742-746
[10]   Transparent Flexible Graphene Triboelectric Nanogenerators [J].
Kim, Seongsu ;
Gupta, Manoj Kumar ;
Lee, Keun Young ;
Sohn, Ahrum ;
Kim, Tae Yun ;
Shin, Kyung-Sik ;
Kim, Dohwan ;
Kim, Sung Kyun ;
Lee, Kang Hyuck ;
Shin, Hyeon-Jin ;
Kim, Dong-Wook ;
Kim, Sang-Woo .
ADVANCED MATERIALS, 2014, 26 (23) :3918-3925