Acceptorless Dehydrogenation of Alcohols: Perspectives for Synthesis and H2 Storage

被引：126

作者：

Friedrich, Anja ^{[1
]}

Schneider, Sven ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85748 Garching, Germany

来源：

CHEMCATCHEM | 2009年 / 1卷 / 01期

关键词：

alcohols; dehydrogenation; oxidation; pincer complexes; ruthenium; OXIDANT-FREE OXIDATION; HOMOGENEOUS RUTHENIUM; CATALYTIC DEHYDROGENATION; HYDROGEN-PRODUCTION; ELECTRON-RICH; SECONDARY ALCOHOLS; LIQUID-PHASE; COMPLEXES; METHANOL; ALDEHYDES;

D O I：

10.1002/cctc.200900124

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Without acception : Acetals are selectively obtained from acceptorless alcohol dehydrogenation (AAD) of aliphatic primary alcohols catalyzed by a rutheni um complex bearing an acridine-based PNP pincer ligand. This unprecedented reaction represents a new tool for one-step acetal synthesis under mild reaction conditions and demonstrates that AAD selectivity can be controlled by changes to the catalyst ligand sphere. © 2009 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

引用

页码：72 / 73

页数：2

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