Two-photon absorption of matrix-free Ge nanocrystals

被引:13
作者
Gerung, Henry [1 ]
Zhao, Yanrui
Wang, Li
Jain, Ravinder K.
Boyle, Timothy J.
Brinker, C. Jeffrey
Han, Sang M.
机构
[1] Univ New Mexico, Dept Chem & Nucl Engn, Farris Engn Ctr 209, Albuquerque, NM 87131 USA
[2] Univ New Mexico, Ctr High Technol Mat, Albuquerque, NM 87106 USA
[3] Sandia Natl Labs, Adv Mat Labs, Albuquerque, NM 87106 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2352711
中图分类号
O59 [应用物理学];
学科分类号
摘要
The authors demonstrate that solution synthesized Ge nanocrystals (NCs) display a highly nonlinear optical absorption. The Ge NCs with an average diameter of 5 +/- 2 nm are synthesized from germanium(II) bis(trimethylsilyl)amide with hexadecylamine surfactants at 300 degrees C and 1 atm in argon atmosphere. The resulting Ge NCs in a powder form are then dispersed on a silica glass substrate. Femtosecond pulses at 820 nm wavelength from a mode-locked Ti:sapphire laser are used to measure a two-photon absorption coefficient of the deposited Ge NCs. The calculated coefficient ranges from 1190 to 1940 cm/GW. (c) 2006 American Institute of Physics.
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页数:3
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