Solvothermal synthesis of CdO and CuO nanocrystals

被引：133

作者：

Ghosh, M

Rao, CNR ^{[1
]}

机构：

[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[2] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[3] Jawaharlal Nehru Ctr Adv Sci Res, CSIR, Ctr Excellence Chem, Bangalore 560064, Karnataka, India

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 393卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2004.06.092

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanocrystals of CdO have been obtained by the decomposition of the cupferron complex in the presence of tri-n-octylphosphine oxide (TOPO) under solvothermal conditions. The precursor:TOPO ratio plays an important role in determining the size of the nanocrystals. The nanocrystals have been characterized by electron microscopy, absorption spectroscopy and fluorescence spectroscopy, besides X-ray diffraction. The CdO nanocrystals are single crystalline and show evidence for quantum confinement. CuO nanocrystals could also be prepared by the decomposition of the cupferronate under solvothermal conditions, the particle size being controlled by the initial precursor concentration. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：493 / 497

页数：5

共 15 条

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