Serine sublimes with spontaneous chiral amplification

被引：76

作者：

Perry, Richard H. ^{[1
]}

Wu, Chunping ^{[1
]}

Nefliu, Marcela ^{[1
]}

Cooks, R. Graham ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 10期

关键词：

D O I：

10.1039/b616196k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sublimation of near-racemic samples of serine yields a sublimate which is highly enriched in the major enantiomer; this simple one-step process occurs under relatively mild conditions, and represents a possible mechanism for the chiral amplification step in homochirogenesis.

引用

收藏

页码：1071 / 1073

页数：3

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