Macrosegregation of Y2BaCuO5 particles in top-seeded melt textured monoliths

被引:23
作者
Delamare, MP
Walter, H
Bringmann, B
Leenders, A
Freyhardt, HC
机构
[1] Univ Gottingen, Inst Mat Phys, D-37073 Gottingen, Germany
[2] Univ Quebec, INRS Energie & Mat, Quebec City, PQ, Canada
[3] Zentrum Funkt Werkstoffe Gottingen, D-37073 Gottingen, Germany
来源
PHYSICA C | 1999年 / 323卷 / 3-4期
关键词
melt-textured superconductors; Y-based cuprates; pushing/trapping; macrosegregation;
D O I
10.1016/S0921-4534(99)00445-1
中图分类号
O59 [应用物理学];
学科分类号
摘要
Y2BaCuO5 (Y-211) particles distributed in the textured matrix play an important role for the superconducting properties. The Top-Seeded Melt Growth (TSMG) process always leads to a macrosegregation of Y-211. For TSMG and Multi-Seeded Melt Growth (MSMG) monoliths, the characterization of the distribution of the Y-211 particles was performed over slices in the (001) plane and (001) direction, respectively. As soon as the growth commences, a zone with a low content of less than 10 mol% of Y-211 appears. The low content of Y-211 can mainly be explained by the pushing/trapping model. This model relates the radii of the smallest trapped Y-211 particles to the growth rate. Furthermore, when the undercooling Delta T reaches 25 degrees C, the growth front stops to push the particles and starts to trap them. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:107 / 114
页数:8
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