LARGE-AREA GRAPHENE-BASED FLEXIBLE TRANSPARENT CONDUCTING FILMS

被引:56
作者
Guenes, Fethullah [1 ]
Han, Gang Hee [1 ]
Kim, Ki Kang [1 ]
Kim, Eun Sung [1 ]
Chae, Seung Jin [1 ]
Park, Min Ho [1 ]
Jeong, Hae-Kyung [1 ]
Lim, Seong Chu [1 ]
Lee, Young Hee [1 ]
机构
[1] Sungkyunkwan Univ, Ctr Nanotubes & Nanostruct Composites, Sungkyunkwan Adv Inst Nanotechnol, Div Phys BK21, Suwon 440746, South Korea
关键词
Large area graphene; chemical vapor deposition; flexible transparent conducting film; CARBON NANOTUBES;
D O I
10.1142/S1793292009001538
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A simple approach by direct synthesis of few-layer graphene sheets and transferring them onto flexible substrate is demonstrated. The hydrogen effect on the D band intensity of Raman spectra for few-layer graphene sheets synthesized by chemical vapor deposition (CVD) on Ni-evaporated silicon substrate is investigated by optimizing the mixing ratio of C2H4/H-2. While the Ni etchant is used to melt away the squeezed Ni layers between graphene sheet and silicon substrate, the graphene sheet is transferred onto polyethylene terephthalate film by a fishing method. It is found that the condition of graphene transfer strongly relies on the cooling rate of the film during CVD synthesis. The sheet resistance of the film decreases as the film thickness increases. A sheet resistance of 233 Omega/sq is obtained at a transmittance of 62%.
引用
收藏
页码:83 / 90
页数:8
相关论文
共 22 条
[1]   Hole Doping to Aligned Single-Walled Carbon Nanotubes from Sapphire Substrate Induced by Heat Treatment [J].
Ago, Hiroki ;
Tanaka, Izumi ;
Tsuji, Masaharu ;
Ikeda, Ken-ichi ;
Mizuno, Seigi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (47) :18350-18354
[2]   GRAPHITE ELECTRODES FOR CONDUCTIVITY MEASUREMENTS ON BETA ALUMINA [J].
BAUKAL, W ;
KNOEDLER, R .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1975, 5 (02) :105-109
[3]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[4]   Graphene-based liquid crystal device [J].
Blake, Peter ;
Brimicombe, Paul D. ;
Nair, Rahul R. ;
Booth, Tim J. ;
Jiang, Da ;
Schedin, Fred ;
Ponomarenko, Leonid A. ;
Morozov, Sergey V. ;
Gleeson, Helen F. ;
Hill, Ernie W. ;
Geim, Andre K. ;
Novoselov, Kostya S. .
NANO LETTERS, 2008, 8 (06) :1704-1708
[5]   The effect of substrates on the Raman spectrum of graphene: Graphene-on-sapphire and graphene-on-glass [J].
Calizo, Irene ;
Bao, Wenzhong ;
Miao, Feng ;
Lau, Chun Ning ;
Balandin, Alexander A. .
APPLIED PHYSICS LETTERS, 2007, 91 (20)
[6]   Replacement of transparent conductive oxides by single-wall carbon nanotubes in Cu(In,Ga)Se2-based solar cells [J].
Contreras, Miguel A. ;
Barnes, Teresa ;
van de lagemaat, Jao ;
Rumbles, Garry ;
Coutts, Timothy J. ;
Weeks, Chris ;
Glatkowski, Paul ;
Levitsky, Igor ;
Peltola, Jorma ;
Britz, David A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (38) :14045-14048
[7]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[8]   Effect of acid treatment on carbon nanotube-based flexible transparent conducting films [J].
Geng, Hong-Zhang ;
Kim, Ki Kang ;
So, Kang Pyo ;
Lee, Young Sil ;
Chang, Youngkyu ;
Lee, Young Hee .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) :7758-+
[9]   A chemical route to graphene for device applications [J].
Gilje, Scott ;
Han, Song ;
Wang, Minsheng ;
Wang, Kang L. ;
Kaner, Richard B. .
NANO LETTERS, 2007, 7 (11) :3394-3398
[10]   Percolation in transparent and conducting carbon nanotube networks [J].
Hu, L ;
Hecht, DS ;
Grüner, G .
NANO LETTERS, 2004, 4 (12) :2513-2517