New optically pure sugar hydroperoxides. Synthesis and use for enantioselective oxygen transfer

被引：68

作者：

Hamann, HJ

Hoft, E

Mostowicz, D

Mishnev, A

UrbanczykLipkowska, Z

Chmielewski, M

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,WARSAW,POLAND

[2] HUMBOLDT UNIV BERLIN,INST CHEM,BERLIN,GERMANY

[3] INST APPL CHEM BERLIN ADLERSHOF,BERLIN,GERMANY

[4] LATVIAN INST ORGAN SYNTH,RIGA,LATVIA

来源：

TETRAHEDRON | 1997年 / 53卷 / 01期

关键词：

D O I：

10.1016/S0040-4020(96)00962-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Deoxy-2-C-methylene methyl glycosides undergo oxidation with hydrogen peroxide in the presence of molybdenum trioxide as catalyst to afford the corresponding anomeric hydroperoxides. These hydroperoxides were used as chiral oxidants of allylic alcohols and prochiral sulfides to offer moderate enantioselectivities which were, however, higher than those reported before for oxidation with optically active peroxyacids. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：185 / 192

页数：8

共 12 条

[1] A NEW FERRIER SYSTEM - 2-C-ACETOXYMETHYLGLYCALS - A CONVENIENT ENTRY TO 2-C-METHYLENE GLYCOSIDES [J].