Photocatalytic water decomposition by RuO2-loaded antimonates, M2Sb2O7 (M = Ca, Sr), CaSb2O6 and NaSbO3, with d10 configuration

被引：128

作者：

Sato, J ^{[1
]}

Saito, N ^{[1
]}

Nishiyama, H ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Nagaoka Univ Technol, Dept Chem, Nagaoka, Niigata 9402188, Japan

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2002年 / 148卷 / 1-3期

关键词：

photocatalysts; water decomposition; alkaline earth metal antimonates; alkaline metal antimonates; the d(10) configuration;

D O I：

10.1016/S1010-6030(02)00076-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photocatalytic activity for water decomposition of alkaline earth metal and alkaline metal antimonates, M2Sb2O7 (M = Ca, Sr), CaSb2O6 and NaSbO3, was investigated. These antimonates were photocatalytically active when combined with RuO2: both H-2 and O-2 were produced from the initial stage of reaction under UV irradiation, and the photocatalytic activity became stable as the reaction proceeded. The photocatalytic properties are discussed based on the distorted structures of SbO6 octahedra. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：85 / 89

页数：5

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