Photoinduced conductivity and nonlinear optical properties of [M(R, R′timdt)2] dithiolenes (M = Ni, Pd, Pt; R,R′timdt = monoreduced imidazolidine-2,4,5-trithione) as materials for optically driven switches and photodetectors

被引:54
作者
Aragoni, MC
Arca, M
Cassano, T
Denotti, C
Devillanova, FA
Isaia, F
Lippolis, V
Natali, D
Nitti, L
Sampietro, M
Tommasi, R
Verani, G
机构
[1] Univ Cagliari, Dipartimento Chim Inorgan & Analit, I-09042 Monserrato, Italy
[2] Univ Bari, Dipartimento Fis, INFM, DETO, I-70126 Bari, Italy
[3] Politecn Milan, Dipartimento Elettr & Informaz, I-20133 Milan, Italy
关键词
Ni; Pd and Pt dithiolenes; NIR; photoconductivity; optoelectronics; IR photodetector; time-resolved saturation dynamics;
D O I
10.1016/S1387-7003(02)00582-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The unusual NIR-photoconducting properties of [M(Et,Pent-timdt)2] neutral dithiolenes (M=Ni, Pd, Pt; Et,Pent-timdt= monoreduced N-ethyl,N'-pentylimidazolidine-2,4,5-trithione) have been investigated with the aim of developing wavelength-selective air-stable photodetectors. In addition, the ps time-resolved dynamics of the absorption saturation has been studied on the Pd-complex by means of pump-probe experiments. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:869 / 872
页数:4
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