Asymmetric amidation of saturated C-H bonds catalysed by chiral ruthenium and manganese porphyrins

被引:121
作者
Zhou, XG [1 ]
Yu, XQ [1 ]
Huang, JS [1 ]
Che, CM [1 ]
机构
[1] Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Peoples R China
关键词
D O I
10.1039/a907653k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral ruthenium(II) and manganese(III) porphyrins catalyse the asymmetric amidation of saturated C-H bonds of ethylbenzene and ethylnaphthalenes to form the corresponding amides in up to 85% yield with 45-58% ee.
引用
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页码:2377 / 2378
页数:2
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