Catalytic and asymmetric aziridination of alkenes catalysed by a chiral manganese porphyrin complex

被引：84

作者：

Lai, TS

Kwong, HL

Che, CM

Peng, SM

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong

[2] City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Hong Kong

[3] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 24期

关键词：

D O I：

10.1039/a706395d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A D-4-manganese(III) porphyrin is utilized to catalyze aziridination of styrene-type substrates with enantiomeric excess ranging from 43 to 68%; evidence for a Mn-IV reactive intermediate in the catalysis was obtained from spectroscopic studies and organic product analysis.

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页码：2373 / 2374

页数：2

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